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The Netherlands: Toxins

Bio-Based Alternatives to Toluene and NMP

| Editor: Alexander Stark

The hazardous substances toluene and nitrogenous NMP are used worldwide at a very large scale as solvents in for example paints, coatings and medicines.
The hazardous substances toluene and nitrogenous NMP are used worldwide at a very large scale as solvents in for example paints, coatings and medicines. (Source: CC0 Pixabay)

The EU is researching whether the use of toluene and NMP, which are considered to be toxic, can be restricted.

Wageningen/The Netherlands — The hazardous substances toluene and nitrogenous NMP are used worldwide at a very large scale as solvents in for example paints, coatings and medicines. In the EU-BBI project Resolve Wageningen Food & Biobased Research is developing safe alternatives for toluene and NMP with technically similar properties. In addition, these alternatives are sustainable, because they are manufactured from vegetable, carbohydrate-rich residual flows

The annual use of NMP and toluene amounts to hundreds of thousands to millions of tonnes, while they are extremely harmful to the health of people working with these substances. These substances feature on the List of Substances of Very High Concern. In this project, the researchers aim to develop technically similar non-toxic alternatives. "We’re cooperating with York University and a dozen European companies in this interesting project," says Laura Thissen of Wageningen Food & Biobased Research.

Novel Approach

When looking for alternatives, substances with a molecular structure similar to toluene and NMP are usually looked at. It is then relatively simple to use these alternatives in current production processes. However, it is quite difficult to develop safe lookalikes, because the toxicity is related to the molecular structure.

Resolve aims for developing alternatives with a completely different chemical structure, avoiding the chemical groups that make toluene and NMP toxic.

Promising Platform Chemicals

Researchers from Wageningen Food & Biobased Research and York University have identified a number of promising bio-based platform chemicals which can be converted into high-quality solvents.

The scientists are looking at carbohydrate-rich residual flows at an industrial scale as source material such as sugar beet pulp, which has a stable quality. This is required for scaling. "We expect to be able to develop fully bio-based alternatives to toluene and NMP," Thissen says.

Major Breakthrough

Thissen expects that the promising bio-based alternatives can be tested at pilot scale level in 2019 or 2020. Then it will also become clear if their production is technically and economically feasible. Toxicological safety testing will be done before scaling up. If Resolve becomes a success, this might cause a breakthrough in the market of solvents.

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